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- W1996572061 abstract "Abstract The reason for the apparent cis -aziridine selectivity in the reaction of ethyl diazoacetate with N -benzylidene aniline, catalyzed by [(η 5 -C 5 H 5 )(CO) 2 Fe(THF)] + [BF 4 ] − , is reported. The catalytic reaction produces both cis and trans -aziridines. Once the imine has been consumed, the trans -isomer is shown to undergo a catalytic decomposition, leaving cis -aziridine and by-products. The reaction is graphically profiled to illustrate the relative quantity of reactants and products as a function of time. A new mechanistic model is proposed in order to explain the observed selectivity." @default.
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- W1996572061 date "2001-07-01" @default.
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- W1996572061 title "An explanation for the apparent cis-aziridine selectivity in the iron Lewis acid-catalyzed reaction of N-benzylidene aniline and ethyl diazoacetate" @default.
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- W1996572061 doi "https://doi.org/10.1016/s0022-328x(01)00886-5" @default.
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