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- W1996636162 abstract "Styrene-acrylonitrile copolymers, like many other copolymers containing styrene, exhibit both normal and excimer fluorescence. We have shown that the ratio of the excimer to monomer fluorescence intensities in random styrene-acrylonitrile copolymers is linearly dependent upon the concentration of styrene-styrene bonds in the copolymer. This observation is consistent with a photophysical model which allows the energy absorbed by styrene units to migrate freely along the copolymer chain. Some of the energy is emitted in the form of normal fluorescence; some of the energy, trapped by neighbouring styrene-styrene pairs suitably oriented to allow excimer formation, is emitted as excimer fluorescence. The fluorescence characteristics of acrylonitrile-styrene copolymers are contrasted with those of methyl methacrylate-styrene copolymers, in which the methylmethacrylate sequences are believed to present partial barriers to energy migration along the copolymer chains." @default.
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- W1996636162 date "1982-01-01" @default.
- W1996636162 modified "2023-09-25" @default.
- W1996636162 title "Sequence distribution and intramolecular excimer formation in styrene-acrylonitrile copolymers" @default.
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- W1996636162 doi "https://doi.org/10.1016/0014-3057(82)90135-5" @default.
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