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• W1996643129 abstract "Abstract Summary: Temperature‐induced and solvent composition‐induced phase separation in solutions of poly( N ‐isopropylmethacrylamide) (PIPMAm) and other thermoresponsive polymers as studied by NMR and infrared (IR) spectroscopy is discussed. The fraction p of phase‐separated units (units with significantly reduced mobility) and subsequently, e.g., thermodynamic parameters characterizing the coil‐globule phase transition induced by temperature, were determined from reduced integrated intensities in high‐resolution 1 H NMR spectra. This approach can be especially useful in investigations of phase separation in solutions of binary polymer systems. Information on behaviour of water during temperature‐induced phase transition was obtained from measurements of 1 H NMR relaxation times of HDO molecules. NMR and IR spectroscopy were used to investigate PIPMAm solutions in water/ethanol (D 2 O/EtOH) mixtures where the phase separation can be induced by solvent composition (cononsolvency). Some differences in globular‐like structures induced by temperature and solvent composition were revealed by these methods." @default.
• W1996643129 created "2016-06-24" @default.
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• W1996643129 date "2011-05-01" @default.
• W1996643129 modified "2023-09-25" @default.
• W1996643129 title "Stimuli-Responsive Polymers in Solution Investigated by NMR and Infrared Spectroscopy" @default.
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• W1996643129 doi "https://doi.org/10.1002/masy.201150503" @default.
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