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- W1996647398 abstract "Potential-pH equilibria and potentiodynamic polarization studies were used to examine the electrochemical behavior of copper in aqueous glycine solutions. Potential-pH diagrams for the copper-water-glycine system were derived at different total copper <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline id=ML1 overflow=scroll> <mml:mo stretchy=false>{</mml:mo> <mml:msub> <mml:mi mathvariant=normal>Cu</mml:mi> <mml:mrow> <mml:mo>T</mml:mo> </mml:mrow> </mml:msub> <mml:mo stretchy=false>}</mml:mo> </mml:math> and glycine <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline id=ML2 overflow=scroll> <mml:mo stretchy=false>{</mml:mo> <mml:msub> <mml:mo>L</mml:mo> <mml:mrow> <mml:mo>T</mml:mo> </mml:mrow> </mml:msub> <mml:mo stretchy=false>}</mml:mo> </mml:math> activities. The diagrams show that glycine significantly extended the solubility range of copper. Polarization experiments were conducted in deaerated and aerated aqueous solutions of <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline id=ML3 overflow=scroll> <mml:msup> <mml:mrow> <mml:mn>10</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>2</mml:mn> </mml:mrow> </mml:msup> <mml:mo>M</mml:mo> </mml:math> glycine with <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline id=ML4 overflow=scroll> <mml:msup> <mml:mrow> <mml:mn>10</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>5</mml:mn> </mml:mrow> </mml:msup> <mml:mo>M</mml:mo> </mml:math> cupric nitrate and <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline id=ML5 overflow=scroll> <mml:msup> <mml:mrow> <mml:mn>10</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>1</mml:mn> </mml:mrow> </mml:msup> <mml:mo>M</mml:mo> </mml:math> glycine with <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline id=ML6 overflow=scroll> <mml:msup> <mml:mrow> <mml:mn>10</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>4</mml:mn> </mml:mrow> </mml:msup> <mml:mo>M</mml:mo> </mml:math> cupric nitrate at pH values between 9 and 12. The results of these experiments are discussed in terms of the relevant potential-pH diagrams. Good correlations were observed. © 2000 The Electrochemical Society. All rights reserved." @default.
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- W1996647398 date "2001-01-01" @default.
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- W1996647398 title "Electrochemistry of Copper in Aqueous Glycine Solutions" @default.
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- W1996647398 doi "https://doi.org/10.1149/1.1344532" @default.
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