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- W1996649640 abstract "In Part I the similarity between the evolution of gas from a liquid, and the evaporation of vapour from a pure liquid, is discussed. Equations are developed which incorporate the energy of cavity formation in the liquid to accommodate the gas molecule, and the interaction energy between the gas and solvent molecules, based on solubility, surface tension and temperature. Experiments for determining the solubilities of helium in three low-vapour-pressure liquids are described in Part II; the results conform to linear plots, according to the equations formulated in Part I. In Part III, the theory of Part I is applied to the solubilities of air (nitrogen and oxygen) in a variety of petroleum oils ranging from heavy lubricating oils to aircraft fuels; reasonably consistent values were obtained for the radii of the gas molecules, the interaction energies and the heats of evolution. Positive and negative temperature coefficients of solubility are explained by the behaviour of linear plots. The conclusion is reached that the variation of gas solubility with temperature is similar in principle to the variation of vapour pressure with temperature, when allowance is made for the surface tension of the liquid and the polarizability of the gas molecule." @default.
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- W1996649640 date "2007-05-04" @default.
- W1996649640 modified "2023-10-18" @default.
- W1996649640 title "Correlation of the solubilities of gases in low-vapour-pressure liquids by an evaporation analogy" @default.
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- W1996649640 doi "https://doi.org/10.1002/jctb.5010031004" @default.
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