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- W1996656570 abstract "Abstract Efficient inclusion of electron‐deficient aromatic guest molecules in an organic solvent utilizing π‐stacking interactions was achieved by using two kinds of macrocyclic boronic esters, 1,4‐naph‐ [2+2] and 1,5‐naph‐ [2+2] , which were easily prepared by self‐assembly of 1,4‐naphthalenediboronic acid ( 3 ) or 1,5‐naphthalenediboronic acid ( 4 ) and racemic tetrol 1 with an indacene framework in a protic solvent. The X‐ray crystallographic analyses revealed that the tilt angles of the two naphthalene rings are different: that of 1,4‐naph‐ [2+2] is about 15° and that of 1,5‐naph‐ [2+2] is about 0°. Owing to the parallel alignment of two aromatic rings, 1,5‐naph ‐[2+2] has a much higher binding ability than 1,4‐naph‐ [2+2] . This knowledge could be useful for the design of the new host molecules in organic solvents." @default.
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- W1996656570 date "2014-02-02" @default.
- W1996656570 modified "2023-10-18" @default.
- W1996656570 title "Enhancement of Host-Guest Interactions Using Rationally Designed Macrocyclic Boronic Esters with a Naphthalene Core" @default.
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- W1996656570 doi "https://doi.org/10.1002/asia.201301577" @default.
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