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- W1996726945 abstract "The mechanism of the second step in the photosensitized cycloaddition reaction of penta-1,4-diene has been investigated. This step, which starts from an aliphatic cyclic intermediate on the first excited triplet (T1) surface, consists of an intersystem crossing from the T1 state to the ground singlet state (So) and ring closure on the So surface. For two possible reaction paths, cross addition and parallel closure, we have calculated by an ab initio MO method, the lowest point on the crossing seam between the So and T1 states, which can be regarded as the transition state for this second step. The triplet cyclic intermediate for cross addition, 2, requires only ca. 1 kcal mol–1 to reach the lowest crossing point accompanied by 90° internal rotation of the terminal methylene group with relatively small changes in the skeletal structure. On the other hand, the triplet cyclic intermediate for parallel closure, 4, requires ca. 5 kcal mol–1, accompanied by a drastic change in the skeletal molecular structure. The calculation confirms that this second step is not the rate-determining step of the entire cycloaddition reaction." @default.
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- W1996726945 date "1993-01-01" @default.
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- W1996726945 title "Triplet–singlet intersystem crossing as the second step of the cycloaddition of triplet penta-1,4-diene. An ab initio MO study" @default.
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- W1996726945 doi "https://doi.org/10.1039/p29930000071" @default.
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