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- W1996747461 abstract "We present a novel approach of using the butylated hydroxytoluene (BHT) antioxidant found in commercial Pluronic F127 samples as a marker of polymer aggregation. The BHT marker was compared to the pyrene dye and static light scattering methods as a way to measure the critical micelle concentration (CMC) and critical micelle temperature (CMT). The n→π(∗) transitions of BHT are sensitive to the microenvironment as demonstrated by plotting the fractional intensities of its excitation (≈280nm) and emission (≈325nm) peaks. BHT is more sensitive to changes in temperature than concentration. The partition coefficient increases ≈40-fold for pyrene compared to ≈2-fold for BHT when the temperature is increased from 25 to 37°C. CMT values determined using the BHT fluorescence decrease with increasing F127 concentration. Our results show that BHT can be used as a reliable marker of changes in the microenvironment of Pluronic F127." @default.
- W1996747461 created "2016-06-24" @default.
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- W1996747461 date "2011-02-01" @default.
- W1996747461 modified "2023-10-16" @default.
- W1996747461 title "Fluorescence of commercial Pluronic F127 samples: Temperature-dependent micellization" @default.
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- W1996747461 doi "https://doi.org/10.1016/j.jcis.2010.10.028" @default.
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