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- W1996754920 abstract "We report the synthesis, crystallization, electrochemistry, X-ray structure and electron density distribution of a methoxy-substituted-tris-phenalenyl based neutral radical (18); the cyclic voltammogram of the compound shows that the strategy of oxygen substitution at 3,7-positions and the utilization of tris-phenalenyls within the silicon complex reduce the electrochemical disproportionation potentials. The crystal structure shows that the radical exists as a 1D π-chain of partially superimposed phenalenyl rings with intermolecular carbon⋯carbon contacts that fall within van der Waals atomic separation. A bond length–bond order regression analysis of the experimental structures shows that the electron density is distributed over two out of the three phenalenyl units." @default.
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- W1996754920 date "2011-01-01" @default.
- W1996754920 modified "2023-10-16" @default.
- W1996754920 title "Synthesis, crystallization, electrochemistry and single crystal X-ray analysis of a methoxy-substituted-tris-phenalenyl based neutral radical" @default.
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- W1996754920 doi "https://doi.org/10.1039/c0jm02397c" @default.
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