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- W1996772623 abstract "Abstract A premixed nitromethane/oxygen/argon flame at low pressure (4.67 kPa) has been investigated using tunable vacuum ultraviolet (VUV) photoionization and molecular-beam mass spectrometry. About 30 flame species including hydrocarbons, oxygenated and nitrogenous intermediates have been identified by measurements of photoionization efficiency spectra. Mole fraction profiles of the flame species have been determined by scanning burner position at some selected photon energies. The results indicate that N 2 and NO are the major nitrogenous products in the nitromethane flame. Compared with previous studies on nitromethane combustion, a number of unreported intermediates, including C 3 H 4 , C 4 H 6 , C 4 H 8 , C 2 H 2 O, C 2 H 4 O, CH 3 CN, H 2 C NH O, C 3 H 3 N and C 3 H 7 N, are observed in this work. Based on our experimental results and previous modeling studies, a detailed oxidation mechanism including 69 species and 314 reactions has been developed to simulate the flame structure. Despite some small discrepancies, the predictions by the modeling study are in reasonable agreement with the experimental results." @default.
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- W1996772623 date "2009-01-01" @default.
- W1996772623 modified "2023-10-01" @default.
- W1996772623 title "An experimental and kinetic modeling study of a premixed nitromethane flame at low pressure" @default.
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- W1996772623 doi "https://doi.org/10.1016/j.proci.2008.06.098" @default.
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