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- W1996800007 abstract "Reaction of aminomethylcavitands with iso(thio)cyanates gives (thio)urea-functionalized resorcinarene cavitands, which represent a novel class of neutral anion receptors. The complexation of halide anions has been studied both with infrared and 1H NMR spectroscopy. The receptors have a small preference for chloride over the other halides; p-fluorophenylthiourea cavitand 8a gives the highest association constant (Kass = 4.7 × 105 M-1 with chloride in CDCl3). A cooperative effect of the ligating (thio)urea moieties is indicated by the lower affinity of the corresponding tris(thio)urea-functionalized cavitands. For the first time facilitated membrane transport of halide anions through supported liquid membranes is achieved." @default.
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- W1996800007 date "1998-06-01" @default.
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- W1996800007 title "(Thio)urea Resorcinarene Cavitands. Complexation and Membrane Transport of Halide Anions" @default.
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- W1996800007 doi "https://doi.org/10.1021/jo972127l" @default.
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