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• W1996806598 abstract "Abstract The ac impedance behaviour of electrochemically grown dendritic Ag three-dimensional electrodeposits grown from aqueous Ag + ion containing solutions has been studied in the blocking regime covering the 1 ⩽ f ⩽ 10 4 Hz frequency range (ω = 2π f ). These deposits exhibit fractal surface and non fractal mass (volume) characteristics. Impedance data displayed as log Z ″ vs. log ω plots show two linear portions with different frequency dispersion exponents = 0.95 ± 0.03 and = 0.67 ± 0.05, respectively. The crossover frequency, ω λ , as determined from those plots, mainly depends on the electrolyte resistivity and, to a minor extent, on the Ag + ion electrodeposition charge. For ω > ω λ , the surface fractal dimension derived from the reciprocal relationship, D s = (1/α) + 1, is D s = 2.45 ± 0.1. This figure agrees with that obtained from the log (area) vs. log (volume) plots." @default.
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• W1996806598 date "1993-08-01" @default.
• W1996806598 modified "2023-09-27" @default.
• W1996806598 title "An ac impedance study of dendritic silver three-dimensional electrodeposits" @default.
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• W1996806598 doi "https://doi.org/10.1016/0013-4686(93)80287-a" @default.
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