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- W1996878486 abstract "Efficient, highly enantioselective syntheses of (+) and (−)-anti-benzo[a]pyrene diol epoxide (BPDE) from 9,10-dihydrobenzo[a]pyrene are described. Initial epoxidation catalyzed by (salen) Mn(III) complex gives 7,8-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (>90% ee). Acid-catalyzed hydration occurs regio- and stereo-selectively to furnish the trans-tetrahydrodiols which are converted into the optically active anti-BPDEs." @default.
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- W1996878486 date "1995-04-01" @default.
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- W1996878486 title "Enantioselective synthesis of the tumorigenic anti-diol epoxide metabolites of benzo[a]pyrene" @default.
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- W1996878486 doi "https://doi.org/10.1016/0040-4039(95)00385-p" @default.
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