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- W1996904718 abstract "In an optical high-pressure cell with sapphire windows and magnetic stirring, phase equilibria in fluid binary mixtures of carbon dioxide + 2,6,10,15,19,23-hexamethyltetracosane (squalane) have been measured up to 423 K and 100 MPa. The critical curve of the mixture starts at the critical point of the pure alkane (Tc = 933 K, pc = 0.51 MPa (calculated values)). With decreasing temperatures the critical curve runs first through a pressure maximum at about 39 MPa and 473 K, then through a pressure minimum at p = (36.3 ± 0.2) MPa and T = (373 ± 2) K, and at last through a temperature minimum at T = (328.2 ± 0.5) K and p = (70.5 ± 2.0) MPa. Finally the critical curve rises steeply to higher pressures with increasing temperatures. The results are discussed from a phase-theoretical point of view and are compared with phase equilibrium data of other carbon dioxide + alkane mixtures. It follows from this discussion that there are continuous transitions between liquid + gas, liquid + liquid, and gas + gas equilibria in these systems." @default.
- W1996904718 created "2016-06-24" @default.
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- W1996904718 date "1975-09-01" @default.
- W1996904718 modified "2023-10-16" @default.
- W1996904718 title "Phase equilibria and critical phenomena in fluid mixtures of carbon dioxide + 2,6,10,15,19,23-hexamethyltetracosane up to 423 K and 100 MPa" @default.
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- W1996904718 doi "https://doi.org/10.1016/0021-9614(75)90088-9" @default.
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