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- W1996916613 abstract "The rate constants of reactions between metal (Co II, Rh III, Cu II, Ni II and Mn II) tetrasulfophthalocyanines (Mtspcn−) and solvated electrons (e−s) have been measured by pulse radiolysis in aqueous methanol solutions. The measured rate constants equal to 0.8–1.8×1010 M−1 s−1 weakly depend on the kind of metal: the high reactivity is strongly connected with the double nitrogen ring characteristic for metal phthalocyanines. The effectivity of electron scavenging by Mtspcn− have also been measured in the frozen systems: ethylene glycol:water:magnesium chloride or lithium chloride. The frozen thin plates were gamma-irradiated and bleached with light. The differential spectra of irradiated and nonirradiated samples were used to determine the efficiency of electron scavenging: high electron scavenging efficiencies were found." @default.
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- W1996916613 date "2003-06-01" @default.
- W1996916613 modified "2023-09-25" @default.
- W1996916613 title "Scavenging of electrons by metal tetrasulfophthalocyanines in liquid and frozen glasses" @default.
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- W1996916613 doi "https://doi.org/10.1016/s0969-806x(03)00056-2" @default.
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