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- W1996928177 abstract "The molar refractions of ten cyano and two oxalato complex salts were measured in the dissolved state using the NaD line. The molar refractions of complex anions were assumed to be given by the sum of (1) the molar refractions of the ligands and the central metal ion in the gaseous state, (2) the polarization of the ligands due to the field of the central metal ion, and (3) the delocalization of electrons by the metal-ligand π-bonding. The estimation of each term was attempted on the assumption that the chief difference between isoelectronic anions, for example Cu(CN)43− and Zn(CN)42−, is that of the valency of the central metal ions and the contribution of delocalization is roughly the same in such a pair. The polarization of a cyanide ion was found to be about 1.6 cc. per unit charge of metal ion for tetrahedral anions and about 0.9 cc. for octahedral ones. The contribution of π-bonding was estimated to be around 3 cc. per metal-ligand bond for both of the above-mentioned cyano complex anions. The small..." @default.
- W1996928177 created "2016-06-24" @default.
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- W1996928177 date "1961-11-01" @default.
- W1996928177 modified "2023-10-17" @default.
- W1996928177 title "Refractometric Study of Some Cyano and Oxalato Complex Anions" @default.
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- W1996928177 doi "https://doi.org/10.1246/bcsj.34.1563" @default.
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