FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1996929007> ?p ?o ?g. }

• W1996929007 endingPage "4237" @default.
• W1996929007 startingPage "4229" @default.
• W1996929007 abstract "Complexes of the type [Ir{η5-3-(CH3COCH2)C6H5OCH2CH2Pt-Bu2-k-P}(alkene)] (alkene = C2H4, 4, C3H6, 5) were prepared by nucleophilic addition of acetone enolate to the “ansa” π-arene/phosphine-type compounds [Ir(alkene)(η6-C6H5OCH2CH2Pt-Bu2-k-P)][BF4] (alkene = C2H4, 1, C3H6, 2) where the arene−phosphine is acting as a formal eight-electron-donor chelate ligand. On the other hand, the related [Ir{η5-3-(C6H5C≡C)C6H5OCH2CH2Pt-Bu2-k-P}(C2H4)] complex (6) was obtained by addition of phenylacetylide to compound 1, but the reaction was not fully completed. Compounds 4 and 5 react with methanol with a C−O bond cleavage process, producing the vinylphosphine complexes [Ir(η5-C6H5O)(alkene)(t-Bu2PCH═CH2)] (alkene = C2H4, 7, C3H6, 8). Compounds 7 and 8 are also obtained by treatment of 1 and 2, respectively, with a basic solution in methanol. The vinyl group in 7 adds methanol to render an ether phosphine, which coordinates in a chelate form, and the final compound isolated was [Ir(OC6H5)(C2H4)(t-Bu2PCH2CH2OMe-k2-O,P)] (9). In addition, the molecular structures of complexes 4 and 7 have been determined by X-ray diffraction methods." @default.
• W1996929007 created "2016-06-24" @default.
• W1996929007 creator A5002042279 @default.
• W1996929007 creator A5008145223 @default.
• W1996929007 creator A5029854285 @default.
• W1996929007 creator A5075898630 @default.
• W1996929007 date "2008-07-31" @default.
• W1996929007 modified "2023-10-06" @default.
• W1996929007 title "C−C Formation and C−O Cleavage Reactions on Hemilabile Arene−Phosphine Ligands in Route to η⁵-Cyclohexadienyl Iridium Compounds^§" @default.
• W1996929007 cites W1023027195 @default.
• W1996929007 cites W104010375 @default.
• W1996929007 cites W1484586714 @default.
• W1996929007 cites W1588545668 @default.
• W1996929007 cites W1847455801 @default.
• W1996929007 cites W1968600668 @default.
• W1996929007 cites W1970263406 @default.
• W1996929007 cites W1971129216 @default.
• W1996929007 cites W1971384065 @default.
• W1996929007 cites W1973634833 @default.
• W1996929007 cites W1975783559 @default.
• W1996929007 cites W1976109081 @default.
• W1996929007 cites W1982414593 @default.
• W1996929007 cites W1983253578 @default.
• W1996929007 cites W1984025256 @default.
• W1996929007 cites W1991663245 @default.
• W1996929007 cites W1991672753 @default.
• W1996929007 cites W1997514182 @default.
• W1996929007 cites W2000396738 @default.
• W1996929007 cites W2001545987 @default.
• W1996929007 cites W2013512725 @default.
• W1996929007 cites W2018852093 @default.
• W1996929007 cites W2020356217 @default.
• W1996929007 cites W2023230673 @default.
• W1996929007 cites W2023667720 @default.
• W1996929007 cites W2031551660 @default.
• W1996929007 cites W2032842297 @default.
• W1996929007 cites W2033414611 @default.
• W1996929007 cites W2036214564 @default.
• W1996929007 cites W2041987035 @default.
• W1996929007 cites W2043635817 @default.
• W1996929007 cites W2059209248 @default.
• W1996929007 cites W2063615096 @default.
• W1996929007 cites W2064370404 @default.
• W1996929007 cites W2069193002 @default.
• W1996929007 cites W2073881108 @default.
• W1996929007 cites W2075659158 @default.
• W1996929007 cites W2084305045 @default.
• W1996929007 cites W2084783229 @default.
• W1996929007 cites W2085439717 @default.
• W1996929007 cites W2086828237 @default.
• W1996929007 cites W2087715948 @default.
• W1996929007 cites W2089530767 @default.
• W1996929007 cites W2089620467 @default.
• W1996929007 cites W2094320168 @default.
• W1996929007 cites W2095008575 @default.
• W1996929007 cites W2108181912 @default.
• W1996929007 cites W2114572737 @default.
• W1996929007 cites W2138624274 @default.
• W1996929007 cites W2141004057 @default.
• W1996929007 cites W2166326232 @default.
• W1996929007 cites W2322929798 @default.
• W1996929007 cites W2395760081 @default.
• W1996929007 cites W2949232828 @default.
• W1996929007 cites W2950309897 @default.
• W1996929007 cites W2950551383 @default.
• W1996929007 cites W2950652147 @default.
• W1996929007 cites W2951297333 @default.
• W1996929007 cites W3004981438 @default.
• W1996929007 cites W4253426650 @default.
• W1996929007 doi "https://doi.org/10.1021/om800402n" @default.
• W1996929007 hasPublicationYear "2008" @default.
• W1996929007 type Work @default.
• W1996929007 sameAs 1996929007 @default.
• W1996929007 citedByCount "4" @default.
• W1996929007 countsByYear W19969290072015 @default.
• W1996929007 countsByYear W19969290072016 @default.
• W1996929007 countsByYear W19969290072017 @default.
• W1996929007 crossrefType "journal-article" @default.
• W1996929007 hasAuthorship W1996929007A5002042279 @default.
• W1996929007 hasAuthorship W1996929007A5008145223 @default.
• W1996929007 hasAuthorship W1996929007A5029854285 @default.
• W1996929007 hasAuthorship W1996929007A5075898630 @default.
• W1996929007 hasConcept C155647269 @default.
• W1996929007 hasConcept C161790260 @default.
• W1996929007 hasConcept C178790620 @default.
• W1996929007 hasConcept C178907741 @default.
• W1996929007 hasConcept C185592680 @default.
• W1996929007 hasConcept C2776254738 @default.
• W1996929007 hasConcept C2777716191 @default.
• W1996929007 hasConcept C2779607525 @default.
• W1996929007 hasConcept C528581852 @default.
• W1996929007 hasConcept C71240020 @default.
• W1996929007 hasConceptScore W1996929007C155647269 @default.
• W1996929007 hasConceptScore W1996929007C161790260 @default.
• W1996929007 hasConceptScore W1996929007C178790620 @default.
• W1996929007 hasConceptScore W1996929007C178907741 @default.
• W1996929007 hasConceptScore W1996929007C185592680 @default.
• W1996929007 hasConceptScore W1996929007C2776254738 @default.

• next