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• W1996947164 abstract "The reaction of C2H5I with photogenerated Fe(CO)4 was followed using time-resolved infrared spectroscopy. Three novel products were detected. On the basis of their carbonyl stretching frequencies, their kinetics, and calculations of their relative energies, these complexes are assigned as IFe(CO)4(C2H5), IFe(CO)3(η2-COC2H5), and IFe(CO)4(COC2H5). Addition of C2H5I to Fe(CO)4 produces IFe(CO)4(C2H5) as the kinetically preferred product, which then converts to IFe(CO)3(η2-COC2H5), the thermodynamically preferred complex. IFe(CO)4(COC2H5) is formed upon addition of CO to IFe(CO)3(η1-COC2H5), a 16-electron complex that is proposed as a common intermediate leading to the three products. Temperature-dependent studies of the kinetics of the decay of IFe(CO)4(COC2H5), the longest lived of the products, indicate that it decarbonylates with an activation energy of ∼20 kcal/mol." @default.
• W1996947164 created "2016-06-24" @default.
• W1996947164 creator A5040436075 @default.
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• W1996947164 date "2005-02-17" @default.
• W1996947164 modified "2023-09-27" @default.
• W1996947164 title "Reactions of Fe(CO)₄ with C₂H₅I in the Gas Phase: Evidence for the Formation of IFe(CO)₄(C₂H₅), IFe(CO)₃(η²-COC₂H₅), and IFe(CO)₄(COC₂H₅)" @default.
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• W1996947164 doi "https://doi.org/10.1021/om0492348" @default.
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