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- W1996950744 abstract "The reaction of lithiated trimethylsilyldiazomethane (LTMSD) with aldehydes and subsequent quenching with TMSCl furnished relatively stable α-silylated diazocompounds. Upon treatment of the α-silylated diazocompounds with Rh2(OAc)4 in refluxing toluene, α-silyl silyl enol ethers were formed from unbranched and branched aliphatic aldehydes through predominantly 1,2-migration of the C−H bond. In contrast, treatment of the α-silylated diazocompounds with Rh2(tfa)4 at room temperature gave α-silyl silyl enol ethers through exclusive and unusual 1,2-migration of the C−C bond. The origin of the selectivity observed from the two catalysts is discussed in relation to early and late transition states." @default.
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- W1996950744 date "2006-02-04" @default.
- W1996950744 modified "2023-09-25" @default.
- W1996950744 title "Ligand-Induced Control of C−H versus Aliphatic C−C Migration Reactions of Rh Carbenoids" @default.
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- W1996950744 doi "https://doi.org/10.1021/ja057739z" @default.
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