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- W1996955912 abstract "The rates of hydrolysis of 22 1-acyl-2-thiohydantoins in aqueous sulfuric acid to give 2-thiohydantoin and a carboxylic acid have been determined. In 0–90% sulfuric acid, hydrolysis takes place by an A-2 mechanism, and the rate reaches a maximum in about 70% acid. In acid more concentrated than about 90%, hydrolysis takes place by an A-1 mechanism, and the rate increases monotonically. Evidence for the two mechanisms comes from Yates r and Bunnett-Olsen [Formula: see text] parameters; from entropies of activation; from pσ and pσ + relations; and from steric effects." @default.
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- W1996955912 date "1972-12-01" @default.
- W1996955912 modified "2023-09-27" @default.
- W1996955912 title "Thiohydantoins. X. Kinetic Studies of the Acid Hydrolysis of 1-Acyl-2-thiohydantoins" @default.
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- W1996955912 doi "https://doi.org/10.1139/v72-597" @default.
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