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- W1996962852 abstract "Die 1H-NMR-Spektren einiger substituierter 1,5-Disilapentane und 1-Oxa-2,6-Disilacyclohexane werden mitgeteilt und bezüglich Struktur und Bindungsverhältnissen am Si-Atom diskutiert. Es zeigt sich, daß die cyclischen Verbindungen in ihren sterischen Eigenschaften modellmäßig als lineare Siloxane mit fixierter Geometrie aufgefaßt werden können. Der geringe Einfluß, den die Sauerstoff-Funktionalität des Si-Atoms auf die chemischen Verschiebungen der SiCH3-Gruppen ausübt, kann auf stärkere (p → d)π-Anteile in der SiO-Bindung, verglichen mit der SiCl-Bindung, zurückgeführt werden. 1H-NMR Studies on Substituted 1,5-Disilapentanes and 1-Oxa-2,6-Disilacyclohexanes The chemical shifts of the title-compounds are given. Considering the cyclic compounds as models of a linear siloxane with fixed geometry some new informations on the structure of these compounds as well as the electronic character of the SiOSi bond in siloxanes emerge. It is shown, that the oxygen-functionality of the siliconatom has a considerable lower influence to the chemical shifts of the SiCH3 groups compared with that of chlorine. An explanation is presented with regard to inductive and (p→d)π effects." @default.
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- W1996962852 date "1973-11-01" @default.
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- W1996962852 title "1H-NMR-spektroskopische Untersuchungen an substituierten 1,5-Disilapentanen und 1-Oxa-2,6-Disilacyclohexanen" @default.
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- W1996962852 doi "https://doi.org/10.1002/zaac.19734020112" @default.
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