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- W1996969600 abstract "O, I say! An N-formylmorpholine (NFM)-modulated one-pot glycosylation was used for the synthesis for construction of 1,2-cis α-glycosidic linkages in the synthesis of the pentasaccharide repeating unit of the O-antigen that is found in Escherichia coli O86. The synthesis of the O-antigen pentasaccharide repeating unit of the cell wall of Gram-negative bacteria Escherichia coli O86 is reported. The synthesis features the use of an N-formylmorpholine (NFM)-modulated glycosylation method for the construction of 1,2-cis α-glycosidic linkages and an [1+1+2] iterative one-pot α-glycosylation strategy to accelerate the assembly of the tetrasaccharide backbone. 1 As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W1996969600 date "2014-06-06" @default.
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- W1996969600 title "Chemical Synthesis of the O-Antigen Repeating Unit of<i>Escherichia coli</i>O86 by an<i>N</i>-Formylmorpholine-Modulated One-Pot Glycosylation Strategy" @default.
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- W1996969600 doi "https://doi.org/10.1002/ajoc.201402057" @default.
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