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- W1996986961 abstract "The hydrosilylation of terminal alkynes by silanes catalyzed by N-heterocyclic carbene platinum(0) complexes has been investigated. The alkynes included 1-octyne and phenylacetylene. The silanes investigated were bis(trimethylsilyloxy)methylsilane, (trimethylsilyloxy)dimethylsilane, tert-butyldimethylsilane, triphenylsilane, phenyldimethylsilane, triethylsilane, and triethoxysilane. X-ray crystal structures for [Pt(N,N‘-dicyclohexylimidazol-2-ylidene)(η2-dimethylacetylenedicarboxylate)2] (8) and [Pt{C(E)C(E)−C(E)C(E)}(N,N‘-dimethylbenzimidazol-2-ylidene)(σ-NCCH3)] (10) (E = CO2Me) have been obtained. A selectivity model, based on structural parameters of the N-heterocyclic carbene, has been devised in order to rationalize the observed regioselectivity obtained. By a judicious choice of catalyst, alkyne, and silane, the regioselectivity of the addition can be controlled." @default.
- W1996986961 created "2016-06-24" @default.
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- W1996986961 date "2006-03-10" @default.
- W1996986961 modified "2023-10-16" @default.
- W1996986961 title "Hydrosilylation of Alkynes Mediated by <i>N-</i>Heterocyclic Carbene Platinum(0) Complexes" @default.
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- W1996986961 doi "https://doi.org/10.1021/om050866j" @default.
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