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- W1997005071 abstract "Abstract A parametric analysis of the Stark-split spectra of Nd 3+ in frozen dilute aqueous solutions of neodymium chloride has been carried out.The similarity of the spectra of Nd 3+ in frozen dilute solutions and in crystals, where the ion is nine-fold coordinated and of approximate D 3h symmetry (Nd 3+ : LaCl 3 , neodymium ethylsulfate and bromate), was used to obtain initial parameter values. Simultaneous diagonalization of the free ion and crystal field hamiltonians resulted in a r.m.s. deviation σ of 11 cm −1 for 50 levels. The resulting crystal field parameters are B 2 0 = 278 ± 19, B 4 0 = −201 ± 39, B b 0 = −946 ± 55 and B 6 6 = 663 ± 43 cm −1 . Selection rules for D 3h are approximately obeyed. The small value of σ, the number of levels accounted for and the fact that the final parameters are not very different from those in the crystals indicate a nine-fold coordination of approximate D 3h symmetry for Nd 3+ in frozen aqueous solutions. The spectra of liquid solutions show by their similarity to the spectra of frozen solutions that the same surroundings exist in the liquid." @default.
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- W1997005071 date "1981-03-01" @default.
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- W1997005071 title "Parametric analysis of the energy levels of Nd3+ in frozen dilute aqueous solutions of neodymium chloride" @default.
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- W1997005071 doi "https://doi.org/10.1016/0301-0104(81)80268-6" @default.
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