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• W1997013310 abstract "Breakdown products of sphingolipids are involved in cell regulaion and exhibit a wide variety of activities related to signal transduction. The backbone of sphingolipids are the sphingosines which have two stereogenic centers. A general, rapid, chemical/chiroptical micromethod based on the bichromophoric CD exciton chirality principle was developed to distinguish all four possible stereoisomers nonambiguously at a level of ca. 1 microgram. A two step derivatization of sphingosines to 1,3-binaphthoate-2-N-naphthimido-sphingosines and subsequent CD measurement provides an unambiguous method to distinguish all four possible stereoisomers on a microscale level." @default.
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• W1997013310 date "1995-07-01" @default.
• W1997013310 modified "2023-09-26" @default.
• W1997013310 title "A two-step chemical and circular dichroic method for assigning the absolute configurations of sphingosines" @default.
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• W1997013310 doi "https://doi.org/10.1016/0040-4039(95)00998-r" @default.
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