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• W1997029337 abstract "The reaction of Ln[N(SiMe3)2]3 with K under N2 in THF forms the dinitrogen complexes {[(Me3Si)2N]2(THF)Ln}2(mu-eta2:eta2-N2) (Ln = Y, Ho, Tm, and Lu) previously available only for lanthanides with highly reducing divalent states, that is, Tm, Dy, and Nd. The Y and Lu complexes are the first diamagnetic complexes of this type. The Ln2N2 moiety is planar, and the 1.268(3) and 1.285(4) A NN distances in these complexes are consistent with the presence of (N2)2-." @default.
• W1997029337 created "2016-06-24" @default.
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• W1997029337 date "2003-12-24" @default.
• W1997029337 modified "2023-10-03" @default.
• W1997029337 title "Reduction of Dinitrogen to Planar Bimetallic M₂(μ<i>-</i>η²:<i>η</i>²-N₂) Complexes of Y, Ho, Tm, and Lu Using the K/Ln[N(SiMe₃)₂]₃ Reduction System" @default.
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• W1997029337 doi "https://doi.org/10.1021/ja036923m" @default.
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