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• W1997073983 abstract "The liquid and solid Raman spectra were measured for the CH3CH2SiCl3-n (CH3)n and CH3CH2CCl3-n (CH3)n (n = 0–3) series of molecules. Rotational isomerism was systematically reinvestigated on the basis of the spectral observation and the normal coordinate treatment. The barriers to internal rotation about the skeletal CSi and CC axes were estimated from the enthalpy difference of isomers and the skeletal torsions. For both the silicon and carbon compounds, the isomer with more methyl-chlorine gauche-dispositions was more stable than the other. The potential constants, V3, for the CH3CH2SiCl3-n (CH3)n (n = 0–3) series of molecules had nearly the same values, but the V3s for the CH3CH2CCl3-n (CH3)n (n = 0–3) series of molecules steeply increased in the order: CCCl3>CCCl2CH3>CCCl(CH3)2>CC(CH3)3. The potential-energy calculation was conducted in order to obtain information on factors for the stability of rotational isomers." @default.
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• W1997073983 date "1980-01-01" @default.
• W1997073983 modified "2023-10-18" @default.
• W1997073983 title "Molecular vibrations and rotational isomerism of chloro(ethyl)silanes and their carbon derivatives CH3CH2YCl3-n(CH3)n (Y = Si and C; n = 0–3)" @default.
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• W1997073983 doi "https://doi.org/10.1016/0584-8539(80)80034-1" @default.
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