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• W1997091800 abstract "Five-coordinate oxorhenium(V) anions with redox-active catecholate ligands deoxygenate stable nitroxyl radicals, including TEMPO•, to afford dioxorhenium(VII) complexes and aminyl radical-derived products. A structural homologue with redox-inert oxalate ligands does not react with TEMPO•. Redox-active ligands are proposed to lower the kinetic barrier to TEMPO• deoxygenation by giving access to 1e− redox steps that are crucial for the formation and stabilization of intermediate species." @default.
• W1997091800 created "2016-06-24" @default.
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• W1997091800 date "2010-03-24" @default.
• W1997091800 modified "2023-10-16" @default.
• W1997091800 title "Deoxygenation of Nitroxyl Radicals by Oxorhenium(V) Complexes with Redox-Active Ligands" @default.
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• W1997091800 doi "https://doi.org/10.1021/ic9024684" @default.
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