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• W1997100900 endingPage "4677" @default.
• W1997100900 startingPage "4669" @default.
• W1997100900 abstract "Disubstituted peptide ferrocenes conjugates were prepared from ferrocenedicarboxylic acid (Fc(OH)2) and glycineethylester. After conversion of the resulting ester Fc(Gly-OEt)2 1 into the corresponding acid Fc(Gly-OH)2 2 by ester hydrolysis, significant structural changes take place in the way the molecules interact with each other. Complex 1 adopts a 1,3′-conformation showing extensive intermolecular H-bonding forming 1-D chains, whereas complex 2 displays a compact 1,2′-conformation in which the NH on one strand engage in strong intramolecular cross-strand H-bonding involving the amide CO on the opposite strand. Additional intermolecular H-bonding in 2 allows the formation of a 2-D net. In essence, ester-deprotection allows us to switch the ferrocene conformation and the H-bonding pattern." @default.
• W1997100900 created "2016-06-24" @default.
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• W1997100900 date "2004-12-01" @default.
• W1997100900 modified "2023-10-05" @default.
• W1997100900 title "Changes in the hydrogen bonding pattern in ferrocene peptides" @default.
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• W1997100900 doi "https://doi.org/10.1016/j.jorganchem.2004.04.017" @default.
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