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- W1997127557 abstract "Nitrogen isotopic fractionation during ammonium adsorption by clay colloids was shown to occur in two time-dependent stages. A rapid 15 N enrichment of the NH 4 + in solution was followed by a gradual depletion until, after an 8- to 10-h equilibrium period, the δ a 15 N of the NH 4 + in solution was approximately 1; this value was significantly lower than the initial value of 2.3 for the NH 4 Cl used in these experiments. The isotopic equilibrium constant (k e ) for the ammonium adsorption reaction was greater than unity, and higher for the Ca 2+ - than K + -saturated clay colloids." @default.
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- W1997127557 date "1978-02-01" @default.
- W1997127557 modified "2023-09-23" @default.
- W1997127557 title "NITROGEN ISOTOPE FRACTIONATION DURING AMMONIUM EXCHANGE REACTIONS WITH SOIL CLAY" @default.
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- W1997127557 doi "https://doi.org/10.4141/cjss78-005" @default.
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