FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997139450> ?p ?o ?g. }

• W1997139450 endingPage "665" @default.
• W1997139450 startingPage "659" @default.
• W1997139450 abstract "Interpolymer complexation between poly(p-vinyl phenol) (PVPh) and poly(ethylene imine) (PEI) in various solvents was studied. By mutual mixing of solutions of PVPh and PEI, precipitates of PVPh/PEI complexes were prepared from methanol, ethanol, cyclohexanone, N,N-dimethylformamide and N,N-dimethylacetamide. However, only polymer blends were obtained from N-methyl-2-pyrrolidone (NMP). It has been found that solvent molecules also participate in hydrogen-bonding interactions, either as donors or acceptors, with a component polymer; the nature of the solvent assumes a profound influence on the degree of the interpolymer association. The glass transition (Tg) behavior of the complexes and the blends were studied by DSC. Both the complex and the blend showed one composition-dependent Tg, indicating its single-phase nature, and the PVPh/PEI blends prepared by casting from NMP are miscible over the entire composition range. The complexes showed higher Tgs in comparison with those of the blends having the same compositions and positive deviations of Tg were observed for the complexes, suggesting that the strength of the interactions between the components in the complex is much higher than that in the blend. FT-IR study revealed that there are hydrogen-bonding interactions between hydroxyl groups of PVPh and N—H groups of PEI in the blends cast from NMP and that the average strength of the hydrogen bond between the hydroxyl groups of PVPh and the N—H groups of PEI in the blend is much higher than that between hydroxyl groups in pure PVPh. A fluorescence study confirmed that there are stronger interactions between PVPh and PEI in ethanol than in NMP. The interpolymer complexation of PVPh with PEI in ethanol reduces the possibility of the formation of excimer between the structural units of PVPh." @default.
• W1997139450 created "2016-06-24" @default.
• W1997139450 creator A5030290474 @default.
• W1997139450 creator A5077106342 @default.
• W1997139450 creator A5086861827 @default.
• W1997139450 date "1997-05-01" @default.
• W1997139450 modified "2023-10-17" @default.
• W1997139450 title "Interpolymer complexes and miscible blends of poly(p-vinyl phenol) and poly(ethylene imine)" @default.
• W1997139450 cites W1835567046 @default.
• W1997139450 cites W1966397822 @default.
• W1997139450 cites W1967599139 @default.
• W1997139450 cites W1989426511 @default.
• W1997139450 cites W1991553520 @default.
• W1997139450 cites W1993007361 @default.
• W1997139450 cites W2009901888 @default.
• W1997139450 cites W2015159524 @default.
• W1997139450 cites W2021246416 @default.
• W1997139450 cites W2021420236 @default.
• W1997139450 cites W2022264633 @default.
• W1997139450 cites W2023633642 @default.
• W1997139450 cites W2028053717 @default.
• W1997139450 cites W2028255190 @default.
• W1997139450 cites W2030314917 @default.
• W1997139450 cites W2031510251 @default.
• W1997139450 cites W2038721479 @default.
• W1997139450 cites W2043700769 @default.
• W1997139450 cites W2050651416 @default.
• W1997139450 cites W2053029474 @default.
• W1997139450 cites W2070542149 @default.
• W1997139450 cites W2080894126 @default.
• W1997139450 cites W2085916321 @default.
• W1997139450 cites W2092826416 @default.
• W1997139450 cites W2095089105 @default.
• W1997139450 cites W2095136632 @default.
• W1997139450 cites W2100663820 @default.
• W1997139450 cites W2137274686 @default.
• W1997139450 cites W2169235704 @default.
• W1997139450 cites W2261607103 @default.
• W1997139450 cites W2329557602 @default.
• W1997139450 cites W320135875 @default.
• W1997139450 cites W4210991526 @default.
• W1997139450 cites W4248781089 @default.
• W1997139450 cites W4298440226 @default.
• W1997139450 cites W4362218351 @default.
• W1997139450 doi "https://doi.org/10.1016/s0014-3057(96)00207-8" @default.
• W1997139450 hasPublicationYear "1997" @default.
• W1997139450 type Work @default.
• W1997139450 sameAs 1997139450 @default.
• W1997139450 citedByCount "34" @default.
• W1997139450 countsByYear W19971394502013 @default.
• W1997139450 countsByYear W19971394502014 @default.
• W1997139450 countsByYear W19971394502015 @default.
• W1997139450 countsByYear W19971394502016 @default.
• W1997139450 countsByYear W19971394502018 @default.
• W1997139450 crossrefType "journal-article" @default.
• W1997139450 hasAuthorship W1997139450A5030290474 @default.
• W1997139450 hasAuthorship W1997139450A5077106342 @default.
• W1997139450 hasAuthorship W1997139450A5086861827 @default.
• W1997139450 hasConcept C112887158 @default.
• W1997139450 hasConcept C122865956 @default.
• W1997139450 hasConcept C15920480 @default.
• W1997139450 hasConcept C161790260 @default.
• W1997139450 hasConcept C178790620 @default.
• W1997139450 hasConcept C185592680 @default.
• W1997139450 hasConcept C187404810 @default.
• W1997139450 hasConcept C188027245 @default.
• W1997139450 hasConcept C192562407 @default.
• W1997139450 hasConcept C2776573223 @default.
• W1997139450 hasConcept C2776701986 @default.
• W1997139450 hasConcept C2780450521 @default.
• W1997139450 hasConcept C2780471494 @default.
• W1997139450 hasConcept C32909587 @default.
• W1997139450 hasConcept C521977710 @default.
• W1997139450 hasConceptScore W1997139450C112887158 @default.
• W1997139450 hasConceptScore W1997139450C122865956 @default.
• W1997139450 hasConceptScore W1997139450C15920480 @default.
• W1997139450 hasConceptScore W1997139450C161790260 @default.
• W1997139450 hasConceptScore W1997139450C178790620 @default.
• W1997139450 hasConceptScore W1997139450C185592680 @default.
• W1997139450 hasConceptScore W1997139450C187404810 @default.
• W1997139450 hasConceptScore W1997139450C188027245 @default.
• W1997139450 hasConceptScore W1997139450C192562407 @default.
• W1997139450 hasConceptScore W1997139450C2776573223 @default.
• W1997139450 hasConceptScore W1997139450C2776701986 @default.
• W1997139450 hasConceptScore W1997139450C2780450521 @default.
• W1997139450 hasConceptScore W1997139450C2780471494 @default.
• W1997139450 hasConceptScore W1997139450C32909587 @default.
• W1997139450 hasConceptScore W1997139450C521977710 @default.
• W1997139450 hasIssue "5" @default.
• W1997139450 hasLocation W19971394501 @default.
• W1997139450 hasOpenAccess W1997139450 @default.
• W1997139450 hasPrimaryLocation W19971394501 @default.
• W1997139450 hasRelatedWork W1978452520 @default.
• W1997139450 hasRelatedWork W2011854874 @default.
• W1997139450 hasRelatedWork W2039248993 @default.
• W1997139450 hasRelatedWork W2066970497 @default.
• W1997139450 hasRelatedWork W2162047632 @default.
• W1997139450 hasRelatedWork W2360899363 @default.

• next