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- W1997153669 abstract "This article describes observations obtained from detailed investigations of the photochemistry of (η5-C5R5)Rh(CO)2 (R = H, Me) and (HBPz*3)Rh(CO)2 (Pz* = 3,5-dimethylpyrazolyl) complexes in hydrocarbon solutions. Photochemical quantum efficiency data have been recorded for ligand photosubstitution and intermolecular Si-H/C-H bond activation processes following excitation at various wavelengths in the visible and near-UV regions. The results obtained, taken in conjunction with prior photochemical measurements (viz. matrix isolation, flash photolysis and low temperature studies in liquefied noble gases) lead to a proposed mechanistic scheme that explains both the ligand photosubstitution and C-H/Si-H bond activation reactions." @default.
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- W1997153669 title "Photochemical mechanisms in intermolecular C-H bond activation reactions of organometallic complexes" @default.
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- W1997153669 doi "https://doi.org/10.1016/0010-8545(94)80035-9" @default.
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