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• W1997166054 abstract "Intercalation of the tris(2,2‘-bipyridine)ruthenium(II) complex cation into a layered silicate (magadiite; the ideal formula is Na2Si14O29·nH2O) was investigated. Since the complex cation did not intercalate by a direct ion exchange reaction with the interlayer sodium ions in an aqueous medium, a crown ether, 15-crown-5, was added in the reactant to promote the ion-exchange reaction. Two possible reaction mechanisms were proposed for the present ion-exchange reaction:  One is a two-step reaction, where 15-crown-5 was first intercalated into the interlayer space of Na−magadiite and exchanged with tris(2,2‘-bipyridine)ruthenium(II) complex cation subsequently. The other is a one-step reaction, where 15-crown-5 forms complex ions with sodium ions deintercalated from the interlayer space and the tris(2,2‘-bipyridine)ruthenium(II) complex cation is intercalated into the interlayer space to compensate the charge balance. The present success opens up new opportunities to introduce organic cations into the interl..." @default.
• W1997166054 created "2016-06-24" @default.
• W1997166054 creator A5061491407 @default.
• W1997166054 creator A5069194623 @default.
• W1997166054 date "1999-05-29" @default.
• W1997166054 modified "2023-09-24" @default.
• W1997166054 title "Intercalation of Tris(2,2‘-bipyridine)ruthenium(II) into a Layered Silicate, Magadiite, with the Aid of a Crown Ether" @default.
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• W1997166054 doi "https://doi.org/10.1021/jp984198+" @default.
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