Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997183670> ?p ?o ?g. }
- W1997183670 endingPage "182" @default.
- W1997183670 startingPage "177" @default.
- W1997183670 abstract "The properties of the hydrated hydroxide ion OH−(aq) stand in sharp contrast to those of most other aqueous ions. Chief among these is its anomalously high mobility, which is shared only by the aqueous hydronium ion H3O+(aq). However, while the transport mechanism of H3O+(aq) is now well understood, the details of OH−(aq) diffusion at ambient conditions are just beginning to emerge, and the effects of temperature on the transport mechanism remain largely unelucidated. Here, we undertake an ab initio molecular dynamics study of the effect of temperature on the solvation and transport of OH−(aq). In addition to revealing new details of the transport process, our analysis provides an explanation for the experimentally observed temperature dependence of the OH−(aq) reorientation time. The calculations reveal a suppression of proton transfer events that underly the structural diffusion process caused by a pronounced change in the population of dominant OH−(aq) solvation complexes." @default.
- W1997183670 created "2016-06-24" @default.
- W1997183670 creator A5068215051 @default.
- W1997183670 creator A5090306776 @default.
- W1997183670 date "2011-08-01" @default.
- W1997183670 modified "2023-09-23" @default.
- W1997183670 title "On the connection between proton transport, structural diffusion, and reorientation of the hydrated hydroxide ion as a function of temperature" @default.
- W1997183670 cites W1576668315 @default.
- W1997183670 cites W1970699034 @default.
- W1997183670 cites W1972310942 @default.
- W1997183670 cites W1973289313 @default.
- W1997183670 cites W1974197525 @default.
- W1997183670 cites W1976778706 @default.
- W1997183670 cites W1991015473 @default.
- W1997183670 cites W1991658240 @default.
- W1997183670 cites W2002033516 @default.
- W1997183670 cites W2007799552 @default.
- W1997183670 cites W2007893417 @default.
- W1997183670 cites W2010317468 @default.
- W1997183670 cites W2012841293 @default.
- W1997183670 cites W2019880457 @default.
- W1997183670 cites W2023271753 @default.
- W1997183670 cites W2025346738 @default.
- W1997183670 cites W2029042254 @default.
- W1997183670 cites W2038935283 @default.
- W1997183670 cites W2039517674 @default.
- W1997183670 cites W2041782224 @default.
- W1997183670 cites W2042793749 @default.
- W1997183670 cites W2045596260 @default.
- W1997183670 cites W2046001409 @default.
- W1997183670 cites W2050725147 @default.
- W1997183670 cites W2054535981 @default.
- W1997183670 cites W2055036655 @default.
- W1997183670 cites W2058698452 @default.
- W1997183670 cites W2059838064 @default.
- W1997183670 cites W2062550747 @default.
- W1997183670 cites W2065329899 @default.
- W1997183670 cites W2067140406 @default.
- W1997183670 cites W2078184681 @default.
- W1997183670 cites W2081673169 @default.
- W1997183670 cites W2083454908 @default.
- W1997183670 cites W2084628727 @default.
- W1997183670 cites W2085588820 @default.
- W1997183670 cites W2086634221 @default.
- W1997183670 cites W2086957099 @default.
- W1997183670 cites W2094676875 @default.
- W1997183670 cites W2099783677 @default.
- W1997183670 cites W2127400370 @default.
- W1997183670 cites W2132001271 @default.
- W1997183670 cites W2155022040 @default.
- W1997183670 cites W2164008457 @default.
- W1997183670 cites W2169513358 @default.
- W1997183670 cites W2171683999 @default.
- W1997183670 cites W2327228009 @default.
- W1997183670 doi "https://doi.org/10.1016/j.cplett.2011.05.066" @default.
- W1997183670 hasPublicationYear "2011" @default.
- W1997183670 type Work @default.
- W1997183670 sameAs 1997183670 @default.
- W1997183670 citedByCount "42" @default.
- W1997183670 countsByYear W19971836702013 @default.
- W1997183670 countsByYear W19971836702014 @default.
- W1997183670 countsByYear W19971836702015 @default.
- W1997183670 countsByYear W19971836702016 @default.
- W1997183670 countsByYear W19971836702017 @default.
- W1997183670 countsByYear W19971836702018 @default.
- W1997183670 countsByYear W19971836702019 @default.
- W1997183670 countsByYear W19971836702020 @default.
- W1997183670 countsByYear W19971836702021 @default.
- W1997183670 countsByYear W19971836702022 @default.
- W1997183670 countsByYear W19971836702023 @default.
- W1997183670 crossrefType "journal-article" @default.
- W1997183670 hasAuthorship W1997183670A5068215051 @default.
- W1997183670 hasAuthorship W1997183670A5090306776 @default.
- W1997183670 hasConcept C121332964 @default.
- W1997183670 hasConcept C145148216 @default.
- W1997183670 hasConcept C147597530 @default.
- W1997183670 hasConcept C147789679 @default.
- W1997183670 hasConcept C148093993 @default.
- W1997183670 hasConcept C149823470 @default.
- W1997183670 hasConcept C159467904 @default.
- W1997183670 hasConcept C178790620 @default.
- W1997183670 hasConcept C179104552 @default.
- W1997183670 hasConcept C184651966 @default.
- W1997183670 hasConcept C185592680 @default.
- W1997183670 hasConcept C2775896084 @default.
- W1997183670 hasConcept C2777325023 @default.
- W1997183670 hasConcept C2992012372 @default.
- W1997183670 hasConcept C41625074 @default.
- W1997183670 hasConcept C54516573 @default.
- W1997183670 hasConcept C55493867 @default.
- W1997183670 hasConcept C62520636 @default.
- W1997183670 hasConcept C69357855 @default.
- W1997183670 hasConcept C97355855 @default.
- W1997183670 hasConcept C99975950 @default.
- W1997183670 hasConceptScore W1997183670C121332964 @default.
- W1997183670 hasConceptScore W1997183670C145148216 @default.
- W1997183670 hasConceptScore W1997183670C147597530 @default.
- W1997183670 hasConceptScore W1997183670C147789679 @default.