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- W1997203762 abstract "Direct catalytic asymmetric vinylogous reactions of an α,β-unsaturated γ-butyrolactam as a donor are described. A homodinuclear Ni2-Schiff base complex promoted a vinylogous Mannich-type reaction of N-Boc imines as well as a vinylogous Michael reaction to nitroalkenes selectively at the γ-position under simple proton-transfer conditions. Vinylogous Mannich adducts were obtained in 5:1→30:1 dr and 99% ee, and vinylogous Michael adducts were obtained in 16:1→30:1 dr and 93−99% ee." @default.
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- W1997203762 date "2010-03-01" @default.
- W1997203762 modified "2023-10-11" @default.
- W1997203762 title "Direct Catalytic Asymmetric Vinylogous Mannich-Type and Michael Reactions of an α,β-Unsaturated γ-Butyrolactam under Dinuclear Nickel Catalysis" @default.
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- W1997203762 doi "https://doi.org/10.1021/ja1002636" @default.
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