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- W1997256723 abstract "Abstract Half-wave reduction potentials of a set of twelve ( E )-4-aryl-4-oxo-2-butenoic acids obtained by direct current polarography in methanol are reported. E 1/2 is correlated with Hammett sigma values as well as with values of frontier molecular orbitals calculated at a semiempirical molecular orbital level. Constant potential electrolysis of a representative compound shows that the first polarographic wave corresponds to one-electron reduction. The isolation of the product proves reduction of the activated double bond." @default.
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- W1997256723 date "2010-01-01" @default.
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- W1997256723 title "Linear free energy relationships of half-wave reduction potentials of (E)-4-aryl-4-oxo-2-butenoic acids" @default.
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- W1997256723 doi "https://doi.org/10.1016/j.tetlet.2009.11.129" @default.
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