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- W1997278003 abstract "A reversible protonation of transition metal hydrides by weak proton donors has been found by NMR spectroscopy. The reactants are mixed at room temperature, but the protonation is induced only at low temperature by an increase of the dielectric constant of a suitably chosen solvent. Under these conditions the decomposition via dihydrogen release is avoided. Thus, the unstable complex [Cp*RuH4(PCy3)]+ was obtained in CDF3/CDF2Cl by protonation of Cp*RuH3(PCy3) with fluorinated alcohols." @default.
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- W1997278003 date "1999-05-01" @default.
- W1997278003 modified "2023-10-16" @default.
- W1997278003 title "Solvent-Assisted Reversible Proton Transfer within an Intermolecular Dihydrogen Bond and Characterization of an Unstable Dihydrogen Complex" @default.
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- W1997278003 doi "https://doi.org/10.1021/ic981320a" @default.
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