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- W1997281312 abstract "The incorporation of an artificial 5-methyl-2,2′-bipyridine nucleoside at the 5′ terminus of an otherwise self-complementary oligonucleotide sequence opens up the opportunity of metal-mediated aggregation of DNA double helices triggered by the addition of the respective metal ions. Interestingly, two-dimensional aggregates (DNA monolayers) are formed in the presence of nickel(II), whereas copper(II) leads to the formation of three-dimensional disc-shaped structures. With iron(II), a coexistence of both types of aggregates had been observed previously. Models are proposed in which these observations are explained based on geometrical considerations. The artificial nucleoside itself represents a rare example for a C1-symmetric chiral derivative of 2,2′-bipyridine, enabling the formation of four isomeric octahedral complexes." @default.
- W1997281312 created "2016-06-24" @default.
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- W1997281312 date "2011-01-01" @default.
- W1997281312 modified "2023-09-26" @default.
- W1997281312 title "Metal-mediated aggregation of DNA comprising 2,2′-bipyridine nucleoside, an asymmetrically substituted chiral bidentate ligand" @default.
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- W1997281312 doi "https://doi.org/10.1039/c0dt01569e" @default.
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