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- W1997331126 abstract "The synthesis and magnetic characterization of pyrazolato-bridged dinuclear complexes [{M(NCS)(4-Phpy)}2(μ-bpypz)2] (Hbpypz = 3,5-bis(2-pyridyl)-pyrazole; 4-Phpy = 4-phenylpyridine; M = Co2+ (1) and Fe2+ (2)) are described together with the X-ray crystal analysis of the cobalt complex. The structure of 1 shows that the desired coordination has been achieved with the cobalt atoms being coordinated to two bpypz to form the dimer. The X-ray diffraction patterns show 1 and 2 to be isomorphous at room temperature. 2 displays a single spin-crossover transition between the [HS–HS] and [LS–LS] states with Tc = 150 K." @default.
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- W1997331126 date "2005-11-01" @default.
- W1997331126 modified "2023-09-23" @default.
- W1997331126 title "Synthesis, structure and magnetic properties of pyrazolate-bridged dinuclear complexes [{M(NCS)(4-Phpy)}2(μ-bpypz)2] (M = Co2+ and Fe2+)" @default.
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- W1997331126 doi "https://doi.org/10.1016/j.poly.2005.03.047" @default.
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