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- W1997343914 abstract "The Raman spectra of molten SnCl2AlkAlCl4 (Alk = Li, Na or Cs) were studied for compositions ranging from pure SnCl2 to pure AlkAlCl4. Spectra of the sample 50.0 mol% SnCl2·CsCl-50.0 mol% ClAlCl4 were also recorded. No interaction between SnCl2 and AlkAlCl4 leading to a specific complex was detected, but the AlCl4− species caused a dissociation of polymeric SnCl2 into smaller and probably monomeric units. The reported catalytic effects of AlkAlCl4 on the formation of CH3SnCl3 from CH3Cl and SnCl2 have been attributed to the formation of SnCl2 monomer. Four peaks observed in the 50.0 mol% SnCl2·CsCl-50.0 mol% CsAlCl4 melt have been assigned to the fundamentals of pyramidal SnCl3−." @default.
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- W1997343914 date "1979-01-01" @default.
- W1997343914 modified "2023-09-26" @default.
- W1997343914 title "Raman studies of SnCl2AlkAlCl4 melts" @default.
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- W1997343914 doi "https://doi.org/10.1016/0022-1902(79)80511-4" @default.
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