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- W1997348247 abstract "Abstract Polyaniline (PANI) doped with p ‐toluene sulfonic acid was synthesized by chemical polymerization method using (NH 4 ) 2 S 2 O 8 as an oxidizing agent. This is a single step polymerization process for the direct synthesis of the conducting emeraldine salt (ES) phase, without the need of doping, dedoping, and redoping of the polymer. Presence of a free carrier tail at higher wavelength, characteristic of extended coil conformation along with a sharp polaronic peak is observed in the UV–vis spectrum of doped PANI in m ‐cresol solvent. FT‐IR studies show the characteristic peaks of ES phase along with a sharp peak at 1120 cm −1 representing vibration band of the dopant ion. Clumps of small fibers resulting in a sponge‐like structure was observed under scanning electron microscope. Thermal studies revealed a three‐step decomposition pattern. Conductivity is found to increase with an increase in the temperature showing “thermal activation behavior.” Decrease in resistance with increasing humidity is observed in a broad range of humidity. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2161–2169, 2005" @default.
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- W1997348247 date "2005-06-30" @default.
- W1997348247 modified "2023-10-10" @default.
- W1997348247 title "Synthesis, characterization, and morphology ofp-toluene sulfonic acid-doped polyaniline: A material for humidity sensing application" @default.
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- W1997348247 doi "https://doi.org/10.1002/polb.20503" @default.
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