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• W1997367461 endingPage "6930" @default.
• W1997367461 startingPage "6926" @default.
• W1997367461 abstract "Abstract The reaction of [ClP(μ‐PMes*)] 2 ( 1 ) with the Lewis acid GaCl 3 yielded a hitherto unknown tetraphosphabicyclo[1.1.0]butan‐2‐ium salt, [Mes*P 4 (Cl)Mes*][GaCl 4 ] ( 3 [GaCl 4 ]), which incorporates a positively charged phosphonium center within its bicyclic P 4 scaffold. The formation of the title compound was studied by means of low‐temperature NMR experiments. This led to the identification of an intermediate cyclotetraphosphenium cation, which was trapped by reaction with dimethylbutadiene (dmb). All of the compounds were fully characterized by experimental and computational methods." @default.
• W1997367461 created "2016-06-24" @default.
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• W1997367461 date "2015-04-17" @default.
• W1997367461 modified "2023-10-18" @default.
• W1997367461 title "Low-Temperature Isolation of the Bicyclic Phosphinophosphonium Salt [Mes*₂P₄Cl][GaCl₄]" @default.
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• W1997367461 doi "https://doi.org/10.1002/anie.201500892" @default.
• W1997367461 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25891039" @default.
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