Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997427454> ?p ?o ?g. }
- W1997427454 endingPage "11088" @default.
- W1997427454 startingPage "11088" @default.
- W1997427454 abstract "The sensitivity of the 1s X-ray emission and high-energy-resolution fluorescence-detected X-ray absorption spectroscopies (XES and HERFD-XAS) to resolve the variations in the chemical state (electronic structure and local coordination) of Br has been investigated for a selected set of compounds including NaBrO3, NH4Br and C2H4Br2 (1,2-dibromoethane). For the Br K-edge XAS, employing the HERFD mode significantly increases the energy resolution, which demonstrates that with a crystal spectrometer used as a detector the absorption technique becomes a more powerful analytical tool. In the case of XES, the experimental results as well as the density functional theory (DFT) modeling both show that the chemical sensitivity of the main 1s diagram emission lines (Kα1,2 and Kβ1,3) is rather limited. However, the valence-to-core (Kβ2) region of XES displays significant shape and intensity variations, as expected for transitions having the same final states as those of photoemission spectroscopy. The spectra are in good agreement with the molecular orbital description delivered by DFT calculations. Calculations for an extended series of Br compounds confirm that valence-to-core XES can serve as a probe for chemical analysis, and, being a hard X-ray photon-in/photon-out technique, it is particularly well-suited for in situ investigations of molecular transformations, even on the ultrafast time scales down to femtosecond time resolution." @default.
- W1997427454 created "2016-06-24" @default.
- W1997427454 creator A5006168283 @default.
- W1997427454 creator A5010814693 @default.
- W1997427454 creator A5046167960 @default.
- W1997427454 creator A5057283732 @default.
- W1997427454 creator A5076475134 @default.
- W1997427454 creator A5088789621 @default.
- W1997427454 date "2013-01-01" @default.
- W1997427454 modified "2023-10-16" @default.
- W1997427454 title "On the sensitivity of hard X-ray spectroscopies to the chemical state of Br" @default.
- W1997427454 cites W116303998 @default.
- W1997427454 cites W1965339983 @default.
- W1997427454 cites W1967102164 @default.
- W1997427454 cites W1968850965 @default.
- W1997427454 cites W1975680050 @default.
- W1997427454 cites W1978178495 @default.
- W1997427454 cites W1981119401 @default.
- W1997427454 cites W1981128690 @default.
- W1997427454 cites W1982996670 @default.
- W1997427454 cites W1985753920 @default.
- W1997427454 cites W1987600645 @default.
- W1997427454 cites W1988273000 @default.
- W1997427454 cites W1992946894 @default.
- W1997427454 cites W1995420123 @default.
- W1997427454 cites W1995718625 @default.
- W1997427454 cites W1998019760 @default.
- W1997427454 cites W2000309069 @default.
- W1997427454 cites W2000391475 @default.
- W1997427454 cites W2002798176 @default.
- W1997427454 cites W2003826505 @default.
- W1997427454 cites W2003925958 @default.
- W1997427454 cites W2010728677 @default.
- W1997427454 cites W2010984301 @default.
- W1997427454 cites W2013183108 @default.
- W1997427454 cites W2015668116 @default.
- W1997427454 cites W2015746140 @default.
- W1997427454 cites W2015953154 @default.
- W1997427454 cites W2016249727 @default.
- W1997427454 cites W2016777147 @default.
- W1997427454 cites W2016898004 @default.
- W1997427454 cites W2019009147 @default.
- W1997427454 cites W2020384772 @default.
- W1997427454 cites W2030350179 @default.
- W1997427454 cites W2032076805 @default.
- W1997427454 cites W2032806166 @default.
- W1997427454 cites W2033981888 @default.
- W1997427454 cites W2036730716 @default.
- W1997427454 cites W2037621685 @default.
- W1997427454 cites W2040327624 @default.
- W1997427454 cites W2040778187 @default.
- W1997427454 cites W2042698725 @default.
- W1997427454 cites W2043402049 @default.
- W1997427454 cites W2043662492 @default.
- W1997427454 cites W2044997589 @default.
- W1997427454 cites W2045009728 @default.
- W1997427454 cites W2046137983 @default.
- W1997427454 cites W2048280922 @default.
- W1997427454 cites W2052328019 @default.
- W1997427454 cites W2052758999 @default.
- W1997427454 cites W2053766911 @default.
- W1997427454 cites W2054816982 @default.
- W1997427454 cites W2054875485 @default.
- W1997427454 cites W2055866138 @default.
- W1997427454 cites W2057059701 @default.
- W1997427454 cites W2057782596 @default.
- W1997427454 cites W2059027800 @default.
- W1997427454 cites W2059156069 @default.
- W1997427454 cites W2064950621 @default.
- W1997427454 cites W2065608038 @default.
- W1997427454 cites W2068535003 @default.
- W1997427454 cites W2069194786 @default.
- W1997427454 cites W2069478134 @default.
- W1997427454 cites W2071063338 @default.
- W1997427454 cites W2071203724 @default.
- W1997427454 cites W2077867145 @default.
- W1997427454 cites W2077908448 @default.
- W1997427454 cites W2078146328 @default.
- W1997427454 cites W2078171437 @default.
- W1997427454 cites W2078926752 @default.
- W1997427454 cites W2079918120 @default.
- W1997427454 cites W2080714163 @default.
- W1997427454 cites W2082113589 @default.
- W1997427454 cites W2082817019 @default.
- W1997427454 cites W2083129861 @default.
- W1997427454 cites W2086957099 @default.
- W1997427454 cites W2091148489 @default.
- W1997427454 cites W2091313104 @default.
- W1997427454 cites W2092903926 @default.
- W1997427454 cites W2094159929 @default.
- W1997427454 cites W2096465965 @default.
- W1997427454 cites W2103400998 @default.
- W1997427454 cites W2103778724 @default.
- W1997427454 cites W2116509677 @default.
- W1997427454 cites W2120915580 @default.
- W1997427454 cites W2122321283 @default.
- W1997427454 cites W2133788583 @default.
- W1997427454 cites W2140304825 @default.