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- W1997439938 abstract "A novel PVC membrane ion-selective electrode based on tribenzyltin(IV) dithiocarbamate [Sn(IV)–TBDTB] as neutral carrier was developed for thiocyanate (SCN−) determination. The electrode exhibits a near-Nernstian response for SCN− with a slope of 62.8±2.0 mV per decade over a wide concentration range 1.0×10−1–2.0×10−6 mol L−1 and a detection limit of 1.0×10−6 mol L−1 in MES–NaOH buffer, pH 6.0, at 25 °C. The electrode prepared with 1.5 wt.% Sn(IV)–TBDTB, 32.5 wt.% PVC and 66.0 wt.% 2-nitrophenyloctyl ether (o-NPOE) shows optimal response characteristics. Anti-Hofmeister selectivity sequence for a series of anions shown by the electrode was as follows: SCN−>Sal−>I−>ClO>phCOO−>CH3COO−>Br−>Cl−>NO>NO>Citrate>SO42−. The useful pH range for the electrode was found to be 3–7 with a response time 30–40 s. The electrode has been used for direct determination of thiocyanate in wastewater with satisfactory results." @default.
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- W1997439938 date "2005-06-01" @default.
- W1997439938 modified "2023-10-18" @default.
- W1997439938 title "Novel Membrane Potentiometric Thiocyanate Sensor Based on Tribenzyltin(IV) Dithiocarbamate" @default.
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- W1997439938 doi "https://doi.org/10.1002/elan.200403209" @default.
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