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• W1997466605 abstract "Surface mass titrations of a self-assembled monolayer (SAM) of 15-mercaptohexadecanoic acid on a gold/quartz crystal microbalance electrode have been performed at various electrode potentials. The apparent pKa of the monolayer, obtained from the pH value at half the total frequency change, shifted in a negative direction from 6.4 at −200 mV to 4.3 at −700 mV vs Ag/AgCl. When potentials more positive than 600 mV were applied, the pKa has a tendency to shift in the positive direction. These results demonstrate that the surface acid/base properties of the SAMs can be controlled by the electrode potential." @default.
• W1997466605 created "2016-06-24" @default.
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• W1997466605 date "2000-08-04" @default.
• W1997466605 modified "2023-09-24" @default.
• W1997466605 title "Electrode Potential Effect on the Surface p<i>K</i>_a of a Self-Assembled 15-Mercaptohexadecanoic Acid Monolayer on a Gold/Quartz Crystal Microbalance Electrode" @default.
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• W1997466605 doi "https://doi.org/10.1021/la991301t" @default.
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