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- W1997476747 abstract "trans-[MoX2(dppe)2] (X = I, Br) act as inner-sphere electron-transfer mediators for the electrocatalytic reduction of organohalides RX to R˙ + X−, at both MoII→ MoI and MoI→ Mo0reduction processes, each of them involving a cathodically induced heterolytic metal–halide bond cleavage with liberation of X− that is followed by addition of RX to the metal. Digital simulation of cyclic voltammetry at a wide range of scan rates allowed to estimate the rate constants of the various chemical steps for both electrocatalytic cycles, which were compared in terms of Mo–X bond dissociation energies, electronic and stereochemical effects." @default.
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- W1997476747 date "2009-01-01" @default.
- W1997476747 modified "2023-09-26" @default.
- W1997476747 title "Electrocatalytic reduction of organohalides mediated by the dihalo-molybdenum phosphinic complexes trans-[MoX2(Ph2PCH2CH2PPh2)2] (X = I, Br)—A mechanistic study by cyclic voltammetry digital simulation" @default.
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- W1997476747 doi "https://doi.org/10.1039/b811393a" @default.
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