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• W1997510168 abstract "Relaxed carbocations yield stressed isomers: The chief mechanistic principles governing the synthesis of positional isomers of DiSpiroFluorene–IndenoFluorene (DSF-IF) have been unveiled. The present work explains the apparent paradox that increased bulkiness of the substituents borne by the fluorene moieties leads to the more encumbered isomer (see figure). These molecules also display different and tunable emission properties of interest for organic electronic applications. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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• W1997510168 date "2009-12-08" @default.
• W1997510168 modified "2023-10-18" @default.
• W1997510168 title "Encumbered DiSpiro[Fluorene-IndenoFluorene]: Mechanistic Insights" @default.
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• W1997510168 doi "https://doi.org/10.1002/chem.200902006" @default.
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