FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997515461> ?p ?o ?g. }

• W1997515461 endingPage "13" @default.
• W1997515461 startingPage "2" @default.
• W1997515461 abstract "X-ray absorption spectroscopy (XAS) and X-ray fluorescence (XRF) were combined in situ to study the ALD-based synthesis of Pt catalysts. This first time combination of synchrotron-based techniques was applied during the (methylcyclopentadienyl)trimethylplatinum/ozone deposition process executed at 150 °C on a silica support. A nucleation delay indicative for nanoparticle formation was observed for Pt loadings below 1 equivalent monolayer. XAS and XRF were recorded simultaneously at different catalyst loadings in this nucleation regime. Analysis of the combined in situ data yielded a quantitative picture of the evolution of the diameter, shape, lattice packing and density of the deposited Pt clusters. Additionally, the degree of oxidation at the cluster surface after the ozone pulse could be monitored. At the early start of the deposition process, Pt adatoms cluster together to form stable nuclei. A strong increase in the density of nuclei is seen below 0.16 equivalent monolayers, after which coalescence gradually occurs. From 0.04 to 0.71 equivalent monolayers, Pt clusters are fcc packed and correspond best to a hemispherical (1 1 1)-truncated cuboctahedral shape. By crosslinking the XRF and XAS data, a linear increase in cluster diameter with Pt loading is observed within this range. The surface of the Pt clusters is shown to be oxidized immediately after the ozone exposure. The degree of surface oxidation remains approximately constant for clusters with a 1–3 nm diameter. This surface oxygen is shown to be crucial for further growth during deposition. The combined application of in situ XRF and XAS thus allowed for an advanced identification of the ALD-deposited Pt nanoparticles." @default.
• W1997515461 created "2016-06-24" @default.
• W1997515461 creator A5025020201 @default.
• W1997515461 creator A5039168166 @default.
• W1997515461 creator A5053121954 @default.
• W1997515461 creator A5053858283 @default.
• W1997515461 creator A5061029364 @default.
• W1997515461 creator A5061128399 @default.
• W1997515461 creator A5063603300 @default.
• W1997515461 creator A5081161746 @default.
• W1997515461 date "2014-06-01" @default.
• W1997515461 modified "2023-10-12" @default.
• W1997515461 title "In situ XAS and XRF study of nanoparticle nucleation during O3-based Pt deposition" @default.
• W1997515461 cites W1532022075 @default.
• W1997515461 cites W1963968125 @default.
• W1997515461 cites W1967645954 @default.
• W1997515461 cites W1970674260 @default.
• W1997515461 cites W1971556061 @default.
• W1997515461 cites W1977016631 @default.
• W1997515461 cites W1981130398 @default.
• W1997515461 cites W1981244477 @default.
• W1997515461 cites W1994690009 @default.
• W1997515461 cites W1995191254 @default.
• W1997515461 cites W1995282448 @default.
• W1997515461 cites W2004878979 @default.
• W1997515461 cites W2009125029 @default.
• W1997515461 cites W2014247540 @default.
• W1997515461 cites W2019902311 @default.
• W1997515461 cites W2024451528 @default.
• W1997515461 cites W2029333568 @default.
• W1997515461 cites W2032306276 @default.
• W1997515461 cites W2033033223 @default.
• W1997515461 cites W2035931858 @default.
• W1997515461 cites W2039358004 @default.
• W1997515461 cites W2040531575 @default.
• W1997515461 cites W2042962315 @default.
• W1997515461 cites W2045562184 @default.
• W1997515461 cites W2046610999 @default.
• W1997515461 cites W2050979359 @default.
• W1997515461 cites W2053512346 @default.
• W1997515461 cites W2054782670 @default.
• W1997515461 cites W2058297054 @default.
• W1997515461 cites W2064866935 @default.
• W1997515461 cites W2070227796 @default.
• W1997515461 cites W2070638674 @default.
• W1997515461 cites W2076695577 @default.
• W1997515461 cites W2082415642 @default.
• W1997515461 cites W2094042444 @default.
• W1997515461 cites W2095261987 @default.
• W1997515461 cites W2105207770 @default.
• W1997515461 cites W2111493681 @default.
• W1997515461 cites W2144531372 @default.
• W1997515461 cites W2157559075 @default.
• W1997515461 cites W2158932701 @default.
• W1997515461 cites W2171385314 @default.
• W1997515461 cites W2314956796 @default.
• W1997515461 cites W2320967269 @default.
• W1997515461 cites W2331628784 @default.
• W1997515461 cites W2332853172 @default.
• W1997515461 cites W2333547160 @default.
• W1997515461 cites W2754663269 @default.
• W1997515461 cites W42033581 @default.
• W1997515461 doi "https://doi.org/10.1016/j.cattod.2014.01.011" @default.
• W1997515461 hasPublicationYear "2014" @default.
• W1997515461 type Work @default.
• W1997515461 sameAs 1997515461 @default.
• W1997515461 citedByCount "31" @default.
• W1997515461 countsByYear W19975154612014 @default.
• W1997515461 countsByYear W19975154612015 @default.
• W1997515461 countsByYear W19975154612016 @default.
• W1997515461 countsByYear W19975154612017 @default.
• W1997515461 countsByYear W19975154612018 @default.
• W1997515461 countsByYear W19975154612019 @default.
• W1997515461 countsByYear W19975154612020 @default.
• W1997515461 countsByYear W19975154612021 @default.
• W1997515461 countsByYear W19975154612022 @default.
• W1997515461 countsByYear W19975154612023 @default.
• W1997515461 crossrefType "journal-article" @default.
• W1997515461 hasAuthorship W1997515461A5025020201 @default.
• W1997515461 hasAuthorship W1997515461A5039168166 @default.
• W1997515461 hasAuthorship W1997515461A5053121954 @default.
• W1997515461 hasAuthorship W1997515461A5053858283 @default.
• W1997515461 hasAuthorship W1997515461A5061029364 @default.
• W1997515461 hasAuthorship W1997515461A5061128399 @default.
• W1997515461 hasAuthorship W1997515461A5063603300 @default.
• W1997515461 hasAuthorship W1997515461A5081161746 @default.
• W1997515461 hasConcept C113196181 @default.
• W1997515461 hasConcept C119824511 @default.
• W1997515461 hasConcept C121332964 @default.
• W1997515461 hasConcept C125287762 @default.
• W1997515461 hasConcept C127413603 @default.
• W1997515461 hasConcept C149792144 @default.
• W1997515461 hasConcept C155672457 @default.
• W1997515461 hasConcept C159985019 @default.
• W1997515461 hasConcept C161790260 @default.
• W1997515461 hasConcept C164866538 @default.
• W1997515461 hasConcept C171250308 @default.
• W1997515461 hasConcept C178790620 @default.

• next