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- W1997521146 abstract "95Mo NMR shifts and coupling constants are related to the ligand properties and stereochemistry of a range of phosphine complexes containing N2 or other N-ligating groups. With comparable co-ligands, the 95Mo shielding decreases in the sequence H− > CO > PR3 > PAr3 > N2 > N3− ⩾ NCAr > NO+ NNR+ > NNR22− > O-ligands, depending on the balance of ligand field strength and nephelauxetic effects. The shielding decreases with increase in MoN bond order from MoN2 to MoNNR2. Trans influences on 1J(95Mo31P) coupling constants are similar for N2 and the phosphines." @default.
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- W1997521146 date "1988-03-01" @default.
- W1997521146 modified "2023-10-14" @default.
- W1997521146 title "95Mo studies of ligands relevant to dinitrogen fixation: NMR spectrochemical series based on 95Mo shielding" @default.
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- W1997521146 doi "https://doi.org/10.1016/0022-328x(88)89093-4" @default.
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