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• W1997533006 abstract "Two novel, stable PdII complexes, compounds 3 and 4, of two 3-hydroxypyridine-2-carbaldehyde thiosemicarbazones, 1 and 2, resp., were prepared from Li2PdCl4. The single-crystal X-ray structure of complex 3 (= [Pd(2)Cl]) shows that the ligand monoanion coordinates in a planar conformation to the metal via the pyridyl N-, the imine N-, and the thiolato S-atoms. Intermolecular H-bonds, π–π, and CH ⋅ ⋅ ⋅ π interactions lead to a two-dimensional supramolecular assembly. The electronic, IR, UV/VIS, and NMR spectroscopic data of the two complexes are reported, together with their electrochemical properties. A sophisticated experimental procedure was used to determine the multiple dissociation constants of the ligands 1 and 2 by UV/VIS titration." @default.
• W1997533006 created "2016-06-24" @default.
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• W1997533006 date "2006-09-01" @default.
• W1997533006 modified "2023-10-18" @default.
• W1997533006 title "Palladium(II) Complexes of the Thiosemicarbazone andN-Ethylthiosemicarbazone of 3-Hydroxypyridine-2-carbaldehyde: Synthesis, Properties, and X-Ray Crystal Structure" @default.
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• W1997533006 doi "https://doi.org/10.1002/hlca.200690187" @default.
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